Yeah Polymorph could be an option we have loads at work. Don't use it that often but did a project with it last week. We get ours from Specialist Crafts.
I'd cast one of those adapters into the knob, take some time to make jig to hold the pot shaft central and vertical and then inject epoxy resin (or other suitable resin - it needs to bond to adapter and knob.
The jig could simply be of thickish material with a hole drilled in the centre the size of pot shaft and the knob located centrally on the other side. A quick CAD drawing will allow you to align knob to hole.