if it's to build up the ports, and welding isn't that practical, try searching for the specialists who do porting works and find out what type of resin / epoxies they use. Might give you more options.
weldiong would be more permanent though.
Aluminium bronze or silicon bronze and an aluminium cyl head wouldn't end well... they're both copper alloys with a melting temp around 400°C higher than aluminium